Interest in Astrophysical Natural Language Processing (NLP) has increased recently, fueled by the development of specialized language models for information extraction. However, the scarcity of annotated resources for this domain is still a significant challenge. Most existing corpora are limited to Named Entity Recognition (NER) tasks, leaving a gap in resource diversity. To address this gap and facilitate a broader spectrum of NLP research in astrophysics, we introduce astroECR, an extension of our previously built Time-Domain Astrophysics Corpus (TDAC). Our contributions involve expanding it to cover named entities, coreferences, annotations related to astrophysical relationships, and normalizing celestial object names. We showcase practical utility through baseline models for four NLP tasks and provide the research community access to our corpus, code, and models.