In this paper, we deal with the estimation problem for the extreme value parameters in the case of stationary β-mixing serials with heavy-tailed distributions. We first introduce two families of estimators generalizing the Hill's estimator. And from those families, three (03) asymptotically unbiased estimators of the extreme value index are established. Our reflection is based on the generalized Jackknife methodology which consists of taking any pair of three special cases of our family of estimators to cancel the bias term. The resulting estimators are also used to deduce three asymptotically unbiased estimators of the extreme quantiles. In a simulation survey, the performance of our proposed methods are compared to alternative estimators recently introduced in the literature. Finally, our methods are applied to high financial losses data in order to estimate the Value-at-Risk of the daily stock returns on the S&P500 index.