We consider the family of rational functions ψw= ∏( xwi - xwi+1 )-1 indexed by words with no repetition. We study the combinatorics of the sums ΨP of the functions ψw when w describes the linear extensions of a given poset P. In particular, we point out the connexions between some transformations on posets and elementary operations on the fraction ΨP. We prove that the denominator of ΨP has a closed expression in terms of the Hasse diagram of P, and we compute its numerator in some special cases. We show that the computation of ΨP can be reduced to the case of bipartite posets. Finally, we compute the numerators associated to some special bipartite graphs as Schubert polynomials.