ND70 Series Basaltic Glass Reference Materials for Volatile Element (H$_2$O , CO$_2$, S, Cl, F) Measurement and the C Ionisation Efficiency Suppression Effect of Water in Silicate Glasses in SIMS - Tout INSP Access content directly
Journal Articles Geostandards and Geoanalytical Research Year : 2024

ND70 Series Basaltic Glass Reference Materials for Volatile Element (H$_2$O , CO$_2$, S, Cl, F) Measurement and the C Ionisation Efficiency Suppression Effect of Water in Silicate Glasses in SIMS

Yves Moussallam
William Henry Towbin
Kenji Shimizu
  • Function : Author
Takayuki Ushikubo
  • Function : Author
Hyun Joo Lee
  • Function : Author
Sarah Shi

Abstract

We present a new set of reference materials, the ND70‐series, for in situ measurement of volatile elements (H$_2$, CO$_2$, S, Cl, F) in silicate glass of basaltic composition. The materials were synthesised in piston cylinders at pressures of 1 to 1.5 GPa under volatile‐undersaturated conditions. They span mass fractions from 0 to 6% m/m H$_2$O, from 0 to 1.6% m/m CO$_2$ and from 0 to 1% m/m S, Cl and F. The materials were characterised by elastic recoil detection analysis for H$_2$O by nuclear reaction analysis for CO$_2$ , by elemental analyser for CO$_2$, by Fourier transform infrared spectroscopy for H$_2$O and CO$_2$ , by secondary ion mass spectrometry for H$_2$, CO$_2$, S, Cl and F, and by electron probe microanalysis for CO$_2$, S, Cl and major elements. Comparison between expected and measured volatile amounts across techniques and institutions is excellent. It was found however that SIMS measurements of CO$_2$ mass fractions using either Cs$^+$ or O$^-$ primary beams are strongly affected by the glass H$_2$O content. Reference materials have been made available to users at ion probe facilities in the US, Europe and Japan. Remaining reference materials are preserved at the Smithsonian National Museum of Natural History where they are freely available on loan to any researcher.

Domains

Geochemistry
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Dates and versions

hal-04662147 , version 1 (25-07-2024)

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Yves Moussallam, William Henry Towbin, Terry Plank, Hélène Bureau, Hicham Khodja, et al.. ND70 Series Basaltic Glass Reference Materials for Volatile Element (H$_2$O , CO$_2$, S, Cl, F) Measurement and the C Ionisation Efficiency Suppression Effect of Water in Silicate Glasses in SIMS. Geostandards and Geoanalytical Research, In press, ⟨10.1111/ggr.12572⟩. ⟨hal-04662147⟩
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